# The Essentials: Properties of Fluids and Thermodynamic Properties and Relationships

### 1.4 Properties of Fluids

A number of ﬂuid properties must be used in our study of ﬂuid mechanics. Density, mass per unit volume, was introduced in Eq. (1.7). We often use weight per unit volume, the speciﬁc weight g, related to density by

γ = ρg                                     (1.11)

where g is the local gravity. For water g is taken as 9810 N/m3 unless otherwise stated. Speciﬁc weight for gases is seldom used.

Speciﬁc gravity S is the ratio of the density of a substance to the density of water and is often speciﬁed for a liquid. It may be used to determine either the density or the speciﬁc weight:

For example, the speciﬁc gravity of mercury is 13.6, which means that it is 13.6 times heavier than water. So, Pmercury = 13.6 × 1000 = 13 600 kg/m , where the density of water is 1000 kg/m3, the common value used for water.

Viscosity m can be considered to be the internal stickiness of a ﬂuid. It results in shear stresses in a ﬂow and accounts for losses in a pipe or the drag on a rocket. It can be related in a one-dimensional ﬂow to the velocity through a shear stress by

where we call du/dr a velocity gradient; r is measured normal to a surface and u is tangential to the surface, as in Fig. 1.4. Consider the units on the quantities in Eq. (1.13): the stress (force divided by an area) has units of N/m2 so that the viscosity has the units N · s/m2.

To measure the viscosity, consider a long cylinder rotating inside a second cylinder, as shown in Fig. 1.4. In order to rotate the inner cylinder with the rotational

Figure 1.4 Fluid being sheared between two long cylinders.

speed Ω, a torque T must be applied. The velocity of the inner cylinder is RΩ and the velocity of the outer ﬁxed cylinder is zero. The velocity distribution in the gap h between the cylinders is essentially a linear distribution as shown so that

We can relate the shear to the applied torque as follows:

where the shear stresses acting on the ends of the long cylinder have been neglected. A device used to measure the viscosity is a viscometer.

In an introductory course, attention is focused on Newtonian ﬂuids, those that exhibit a linear relationship between the shear stress and the velocity gradient, as in Eqs. (1.13) and (1.14) and displayed in Fig. 1.5 (the normal coordinate here is y). Many common ﬂuids, such as air, water, and oil are Newtonian ﬂuids. Non-Newtonian ﬂuids are classiﬁed as dilatants, pseudoplastics, and ideal plastics and are also displayed.

A very important effect of viscosity is to cause the ﬂuid to stick to a surface, the no-slip condition. If a surface is moving extremely fast, as a satellite entering the atmosphere, this no-slip condition results in very large shear stresses on the surface; this results in extreme heat which can incinerate an entering satellite. The no-slip

Figure 1.5 Newtonian and non-Newtonian ﬂuids.

condition also gives rise to wall shear in pipes resulting in pressure drops that require pumps spaced appropriately over the length of a pipe line transporting a ﬂuid such as oil or gas.

Viscosity is very dependent on temperature. Note that in Fig. C.1, the viscosity of a liquid decreases with increased temperature, but the viscosity of a gas increases with increased temperature. In a liquid, the viscosity is due to cohesive forces, but in a gas, it is due to collisions of molecules; both of these phenomena are insensitive to pressure. So we note that viscosity depends on only temperature in both a liquid and a gas, i.e.,μ= μ(T).

The viscosity is often divided by density in equations so we have deﬁned the kinematic viscosity to be

It has units of m2/s. In a gas, we note that kinematic viscosity does depend on pres- sure since density depends on both temperature and pressure.

The volume of a gas is known to depend on pressure and temperature. In a liquid, the volume also depends slightly on pressure. If that small volume change (or den- sity change) is important, we use the bulk modulus B, deﬁned by

The bulk modulus has the same units as pressure. It is included in Table C.1. For water at 20°C it is about 2100 MPa. To cause a 1% change in the volume of water, a pressure of

21 000 kPa is needed. So, it is obvious why we consider water to be incompressible. The bulk modulus is also used to determine the speed of sound c in water. It is given by

This yields about c = 1450 m/s for water at 20°C.

Another property of occasional interest in our study is surface tension s. It results from the attractive forces between molecules, and is included in Table C.1. It allows steel to ﬂoat, droplets to form, and small droplets and bubbles to be spherical. Con- sider the free-body diagram of a spherical droplet and a bubble, as shown in Fig. 1.6. The pressure force inside the droplet balances the force due to surface tension around the circumference:

Figure 1.6 Free-body diagrams of (a) a droplet and (b) a bubble.

Notice that in a bubble there are two surfaces so that the force balance provides

So, if the internal pressure is desired, it is important to know if it is a droplet or a bubble.

A second application where surface tension causes an interesting result is in the rise of a liquid in a capillary tube. The free-body diagram of the water in the tube is shown in Fig. 1.7. Summing forces on the column of liquid gives

Figure 1.7 The rise of a liquid in a small tube.

where the right-hand side of the equation is the weight W. This provides the height the liquid will climb in the tube:

The ﬁnal property to be introduced in this section is vapor pressure. Molecules escape and reenter a liquid that is in contact with a gas, such as water in contact with air. The vapor pressure is that pressure at which there is equilibrium between the escaping and reentering molecules. If the pressure is below the vapor pressure, the molecules will escape the liquid; it is called boiling when water is heated to the temperature at which the vapor pressure equals the atmospheric pressure. If the local pressure is decreased to the vapor pressure, vaporization also occurs. This can happen when liquid ﬂows through valves, elbows, or around turbine blades, should the pressure become sufﬁciently low; it is then called cavitation. The vapor pressure is found in Tables C.1 and C.5.

EXAMPLE 1.3

A 0.5 m × 2 m ﬂat plate is towed at 5 m/s on a 2-mm-thick layer of SAE-30 oil at 38°C that separates it from a ﬂat surface. The velocity distribution between the plate and the surface is assumed to be linear. What force is required if the plate and surface are horizontal?

Solution

The velocity gradient is calculated to be

The force is the stress multiplied by the area:

Check the units to make sure the units of the force are newtons. The viscosity of the oil was found in Fig. C.1.

EXAMPLE 1.4

A machine creates small 1.0-mm-diameter bubbles of 20°C-water. Estimate the pressure that exists inside the bubbles.

Solution

Bubbles have two surfaces leading to the following estimate of the pressure:

where the surface tension was taken from Table C.1.

### 1.5 Thermodynamic Properties and Relationships

A course in thermodynamics and/or physics usually precedes a ﬂuid mechanics course. Those properties and relationships that are presented in those courses that are used in our study of ﬂuids are included in this section. They are of particular use when compressible ﬂows are studied, but they also ﬁnd application to liquid ﬂows.

We use the ideal-gas law in one of the two forms

where the pressure p and the temperature T must be absolute quantities. The gas constant R is found in Table C.4.

Enthalpy is deﬁned as

where u is the speciﬁc internal energy (we use u since u is used for a velocity component). In an ideal gas we can use

where cp and cv are the speciﬁc heats also found in Table C.4. The speciﬁc heats are related to the gas constant by

For liquids and solids, and for most gases over relatively small temperature differences, the speciﬁc heats are essentially constant and we can use

For adiabatic (no heat transfer) quasiequilibrium (properties are constant throughout the volume at an instant) processes the following relationships can be used for an ideal gas assuming constant speciﬁc heats:

The adiabatic, quasiequilibrium process is also called an isentropic process.

A small pressure wave with a relatively low frequency travels through a gas with a wave speed of

Finally, the ﬁrst law of thermodynamics, which we will refer to simply as the energy equation, will be of use in our study; it states that when a system, a ﬁxed set of ﬂuid particles, undergoes a change of state from state 1 to state 2, its energy changes from E to E as it exchanges energy with the surroundings in the form of work W1-2 and heat transfer Q1-2. This is expressed as

To calculate the heat transfer from given temperatures and areas, a course on heat transfer is required, so it is typically a given quantity in thermodynamics and ﬂuid

mechanics. The work, however, is a quantity that can often be calculated; it is a force times a distance and is often due to the pressure resulting in

The energy E considered in a ﬂuids course consists of kinetic energy, potential energy, and internal energy:

where the quantity in the parentheses is the speciﬁc energy e. If the properties are constant at an exit and an entrance to a ﬂow, and there is no heat transferred and no losses, the above equation can be put in the form

This equation does not follow directly from Eq. (1.31); it takes some effort to derive Eq. (1.34). An appropriate text could be consulted, but we will present it later in this book. It is presented here as part of our review of thermodynamics.

EXAMPLE 1.5

A farmer applies nitrogen to a crop from a tank pressurized to 1000 kPa absolute at a temperature of 25°C. What minimum temperature can be expected in the

nitrogen if it is released to the atmosphere?

Solution

The minimum exiting temperature occurs for an isentropic process [see Eq. (1.29)]; it is

Such a low temperature can cause serious injury should a hose break and the nitrogen impact the farmer.

### Quiz No. 1

1. The correct units on viscosity are

(A) kg/(s · m)

(B) kg · m/s

(C) kg · s/m

(D) kg · m/s2

2. The mean free path of a gas is λ = 0.225m/(ρd 2 ) where d is the molecule’s diameter, m is its mass, and r the density of the gas. Calculate the mean free path of air at sea level. For an air molecule d = 3.7 × 10−10 m and m = 4.8 × 10−26 kg.

(A) 0.65×10−7 mm

(B) 6.5×10−7 m

(C) 65 nm

(D) 650 μm

3. A vacuum of 25 kPa is measured at a location where the elevation is 4000 m. The absolute pressure, in millimeters of mercury, is nearest

(A) 425 mm

(B) 375 mm

(C) 325 mm

(D) 275 mm

4. The equation is a good approximation to the pressure in the atmosphere. Estimate the pressure at 6000 m using this equation and calculate the percent error assuming p = 100 kPa and T0  = 15°C. (The more accurate value is found in Table C.3.)

(A) 4.4%

(B) 4.0%

(C) 3.2%

(D) 2.6%

5. A ﬂuid mass of 1500 kg occupies 2 m3. Its speciﬁc gravity is nearest

(A) 1.5

(B) 0.75

(C) 0.30

(D) 0.15

6. A viscometer is composed of two 12-cm-long, concentric cylinders with radii 4 and 3.8 cm. The outer cylinder is stationary and the inner one rotates. If a torque of 0.046 N · m is measured on the inner cylinder at a rotational speed of 120 rpm, estimate the viscosity of the liquid. Neglect the contribution to the torque from the cylinder ends and assume a linear velocity proﬁle.

(A) 0.127 N · s/m2

(B) 0.149 N · s/m2

(C) 0.161 N · s/m2

(D) 0.177 N · s/m2

7. A 0.1-m3 volume of water is observed to be 0.0982 m3 after a pressure is applied. What is that pressure?

(A) 37.8 MPa

(B) 24.2 MPa

(C) 11.7 MPa

(D) 8.62 MPa

8. The pressure inside a 20-μm-diameter bubble of 20°C water is nearest

(A) 17.8 kPa

(B) 24.2 kPa

(C) 29.4 kPa

(D) 38.2 kPa

9. A car with tires pressurized to 270 kPa (40 psi) leaves Phoenix with the tire temperature at 60°C. Estimate the tire pressure (gage) when the car arrives in Alaska with a tire temperature of –30°C.

(A) 270 kPa

(B) 210 kPa

(C) 190 kPa

(D) 170 kPa

10. Air at 22°C is received from the atmosphere into a 200 cm3 cylinder.

Estimate the pressure and temperature (MPa, °C) if it is compressed isentropically to 10 cm3.

 (A) (6.53, 705) (B) (5.72, 978) (C) (4.38, 978) (D) (7.43, 705)

11. Lightning is observed and thunder is heard 1.5 s later. About how far away did the lightning occur?

(A) 620 m

(B) 510 m

(C) 430 m

(D) 370 m

### Quiz No. 2

1. If force, length, and time are selected as the three fundamental dimensions, what are the dimensions on mass?

2. A pressure of 28 kPa is measured at an elevation of 2000 m. What is the absolute pressure in mm of Hg?

3. Water at 20°C ﬂows in a 0.8-cm-diameter pipe with a velocity distribution of  u(r) = 5[1 − (r 2 /16) × 106 ] m/s. Calculate the shear stress on the pipe wall.

4. SAE-30 oil at 30oC ﬁlls the gap between a 40-cm-diameter ﬂat disk rotating

0.16 cm above a ﬂat surface. Estimate the torque needed to rotate the disk at 600 rpm.

5. Water at 30°C is able to climb up a clean glass 0.2-mm-diameter tube due to surface tension. The water/glass angle is 0° with the vertical. How far up the tube does the water climb?

6. Derive an equation that relates the vertical force F needed to just lift a thin wire loop from a liquid assuming a vertical surface tension force. The wire radius is r and the loop diameter is D. Assume D >> r.

7. A 2-m-long, 4 cm-diameter shaft rotates inside an equally long

4.02-cm-diameter cylinder. If SAE-10W oil at 25°C ﬁlls the gap between the concentric cylinders, estimate the horsepower needed to rotate the shaft at 1200 rpm assuming a linear velocity proﬁle.

8. The coefﬁcient of thermal expansion aT allows the expansion of a liquid to be determined using the equation Δ V = αT V ΔT. What pressure is needed to cause the same decrease in volume of 2 m3 of 40°C water as that caused

by a 10°C drop in temperature?

9. Calculate the weight of the column of air contained above a 1-m2 area of atmospheric air from sea level to the top of the atmosphere.

10. Air expands from a tank maintained at 18°C and 250 kPa to the atmosphere. Estimate its minimum temperature as it exits.